Unable to synchronize system time, Pi-hole not working

Have you installed the latest Raspbian/Pi-OS Bullseye?

lsb_release -d

If so, make sure you do below:

Pi-hole needs to be the only DNS server for your clients:

Check on this Win client what DNS servers are configured:

netsh interface ip show dnsservers

Or run below on this Win client to see what server it prefers currently:

nslookup pi.hole