When checking pi.hole, after waking up for the night, there are about 8,000 'requests' from www.googleadservices.com being blocked. It starts around 22:00 and ends around 3:00.
Try configure the router like described in below FAQ instead of pointing the WAN DNS part of the router to Pi-hole.
That way you'll be able to see from which device/IP those DNS queries are coming from.
Thank you very much for offering your assistance on this request. I really appreciate your willingness to help out.
Reading the FAQs better and saw
"Log into your router’s configuration page and find the DHCP/DNS settings. Note: make sure you adjust this setting under your LAN settings and not the WAN."
My router GUI (r7000) doesn't seem to have a LAN DNS, just a "internet" DNS.
Yeah, if the router doesnt have settings to push Pi-hole's IP address to the clients as a DNS server through DHCP, thats the only alternative if want to figure out which device is doing those DNS queries: