If there is no IPv6 solution for this type of modem, try enable below option:
But dont enable below one:
And let Pi-hole take over DHCP for your network:
Copy IP range and gateway from the router DHCP settings over to Pi-hole.
Release DHCP lease on the Win PC:
ipconfig /release
And renew:
ipconfig /renew
And check DNS servers assigned:
ipconfig /all
EDIT: ow is better to enable Pi-hole DHCP first before disabling the router DHCP!
EDIT2: ow and disable as many IPv6 settings on the LAN side as possible (dont touch the WAN/Internet settings) !