I've read Setting Up up a Bridged Wireless Access Point and several other posts on the topic on reddit and here, but most people trying to accomplish this are doing it on a fresh new setup with a more modern device, so the methods are failing for me as I am working with an older device and a lot of network settings are already in place on both my router and device.
I basically just want to have the currently unoccupied ethernet port of my RPi2 work as a means by which to pass Wi-Fi connectivity from the Pi to a device over a cable.
That is not about Pi-hole or Customizing Pi-hole, it is about your OS's network configuration.
While I've recategorised your topic to Community Help, you may also want to consider consulting additional forums or support channels for your OS that specialise in networking.
My two cents. By adding bridging capabilities, traffic will be significantly increased 'through' your pi. With just pi-hole, the much lighter, DNS-only traffic is all it has to manage/serve. Performance, for pi-hole and even your bridged traffic, could suffer if usage is high enough.