Pi-hole displays Active Clients, but does not receive large numbers of queries or block content

Are you sure your devices are configured to use Pi-hole?

Your router is advertising external DNS server to your devices:

dns-server: 75.75.75.75
dns-server: 75.75.76.76

You need to configure each individual device to use Pi-hole as DNS server, or change the DNS servers in your router DHCP/LAN settings.

Try this: