This is a reverse IP lookup (PTR). The requesting client is asking "what is the name of the domain associated with the IP which is listed backwards". It is not a request from that IP.
In this case, it is likely Pi-hole finding out the name of the DNS server at IP 208.67.222.222.
I suspect this is your upstream DNS server in Pi-hole. Pi-hole looks for this name so it can populate the name in the DNS server pie chart on the main page of the web admin GUI (the dashboard).
So, normal, right? I get lost in networking. Took many hours (!) for me to get Pi-hole up and running.
I did see some arguments that this I.p. Could be problematic - "port scans." But Cisco's site turned up nothing nefarious. Sanpme for blacklists. Nonetheless, the apparent location being China causes some chills to go up and down my spine.
Thanks for the quick feedback.
After thought: I'm on a comcast "business" hookup so I googled comcast 222.222.67.208.