This time without Zentyal, set IP addresses manually, and set what I consider the appropriate settings with Webmin (will screenshot if requested)
Windows 10 says the IP configuration is invalid.
I think it's getting the IPv6 address from either the router, or from the 192 interface. I care so little about IPv6, so if I can get help to generate one for the interface I wish it to serve DHCP from, that would be a great help.
I know I need to run some commands, but what, I do not know. I think I have reinstalled at least 8 times now, trying to get this to work.
I was using Zentyal before as a step to assign IP addresses, but this was getting in the way of DNS and DHCP, although disabled
There are several problems shown in your debug log, likely related to your network setup. You have the Pi-Hole and network on three different IP ranges (169.254.17.x, 192.168.0.x, 172.16.0.x).
The Pi-Hole is properly resolving domains from within it's loopback address, so that function works. The problem lies with the Pi-Hole communicating to your network.
Have you had Pi-Hole working properly prior to attempting a dual interface setup? If not, I recommend you do so. Then, once your Pi-Hole is working properly, expand it to dual NIC.
*** [ DIAGNOSING ]: Networking
[✓] IPv4 address(es) bound to the enx0014d1daa277 interface:
169.254.17.7/16 does not match the IP found in /etc/pihole/setupVars.conf (https://discourse.pi-hole.net/t/use-ipv6-ula-addresses-for-pi-hole/2127)
[i] Default IPv4 gateway: 192.168.0.1
* Pinging 192.168.0.1...
[✗] Gateway did not respond. (https://discourse.pi-hole.net/t/why-is-a-default-gateway-important-for-pi-hole/3546)
[i] Default IPv6 gateway: fe80::9221:6ff:fe95:f0a4
* Pinging fe80::9221:6ff:fe95:f0a4...
[✗] Gateway did not respond. (https://discourse.pi-hole.net/t/why-is-a-default-gateway-important-for-pi-hole/3546)
*** [ DIAGNOSING ]: Name resolution (IPv4) using a random blocked domain and a known ad-serving domain
[✓] ad.doubleclick.net.57933.9418.302br.net is 0.0.0.0 via localhost (127.0.0.1)
[✗] Failed to resolve ad.doubleclick.net.57933.9418.302br.net via Pi-hole (172.16.0.1)
[✓] doubleclick.com is 216.58.212.110 via a remote, public DNS server (8.8.8.8)
*** [ DIAGNOSING ]: Name resolution (IPv6) using a random blocked domain and a known ad-serving domain
[✓] agenciaclose.com is :: via localhost (::1)
[✗] Failed to resolve agenciaclose.com via Pi-hole (fd6e:edf8:1b69:0:203:dff:fe9b:bc59)
[✓] doubleclick.com is 2a00:1450:4009:80c::200e via a remote, public DNS server (2001:4860:4860::8888)
*** [ DIAGNOSING ]: Setup variables
PIHOLE_INTERFACE=enx0014d1daa277
IPV4_ADDRESS=172.16.0.1/24
IPV6_ADDRESS=fd6e:edf8:1b69:0:203:dff:fe9b:bc59
....
DHCP_ACTIVE=true
DHCP_START=172.16.0.3
DHCP_END=172.16.0.254
DHCP_ROUTER=172.16.0.1
-rw-r--r-- 1 root root 120 Sep 19 20:32 /etc/pihole/local.list
192.168.0.2 mark
fd6e:edf8:1b69:0:203:dff:fe9b:bc59 mark
192.168.0.2 pi.hole
fd6e:edf8:1b69:0:203:dff:fe9b:bc59 pi.hole