Setting up a temporary 2nd instance of pihole - port conflicts?

I will comment on the "etc.":

This sounds like you want to configure your replacement Pi-hole with the same IP address than the old one, right? So you don't have to go to the router settings and change the address.

This may very well result in a (serious) conflict as no address is allowed to exist twice. So, when changing the IP address of the replacement, make sure to disconnect the first one before the two-devices-using-one-address issue arises. I'd likely take your entire network down, otherwise.