Pihole + Unbound not blocking ads

Pi-hole is working, but you disabled the Default Group (enabled=0 means disabled):

** [ DIAGNOSING ]: Groups
   id    enabled  name                                                date_added           date_modified        description                                       
   ----  -------  --------------------------------------------------  -------------------  -------------------  --------------------------------------------------
   0        0     Default                                             2024-09-28 17:10:24  2025-01-06 19:59:44  The default group                                 

Since you only have one group with one list and this group is disabled, Pi-hole is not blocking.

Enable the Default group and it will start to block.