You have several choices:
- Use Pi-Hole as your DHCP server, and turn off the DHCP on the router (not all routers support this option):
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Manually map clients to Pi-Hole (you can't do this on some clients like IOT devices).
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Figure out the settings on your router, or even put your current router in bridge mode and put a different router on the network to run NAT and DHCP services.