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First, get rid of the 69 lists, that will negate the need for 4893 white/black listings.
Then fix your network:
*** [ DIAGNOSING ]: Networking
[✓] IPv4 address(es) bound to the eth0 interface:
192.168.1.240/24 does not match the IP found in /etc/pihole/setupVars.conf (https://discourse.pi-hole.net/t/use-ipv6-ula-addresses-for-pi-hole/2127)
192.168.2.2/24 matches the IP found in /etc/pihole/setupVars.conf
[✓] IPv6 address(es) bound to the eth0 interface:
fe80::9488:7266:478e:3afb does not match the IP found in /etc/pihole/setupVars.conf (https://discourse.pi-hole.net/t/use-ipv6-ula-addresses-for-pi-hole/2127)
^ Please note that you may have more than one IP address listed.
As long as one of them is green, and it matches what is in /etc/pihole/setupVars.conf, there is no need for concern.
The link to the FAQ is for an issue that sometimes occurs when the IPv6 address changes, which is why we check for it.
Once you're on a sane configuration then see if the problem still exists.
The interface (eth0) has two IP addresses. 192.168.2.2 and 192.168.1.240
You also have two DHCP servers, it seems:
*** [ DIAGNOSING ]: Discovering active DHCP servers (takes 10 seconds)
Scanning all your interfaces for DHCP servers
Timeout: 10 seconds
* Received 300 bytes from eth0:192.168.2.1
Offered IP address: 192.168.2.2
Server IP address: 192.168.2.1
Relay-agent IP address: N/A
BOOTP server: (empty)
BOOTP file: (empty)
DHCP options:
Message type: DHCPOFFER (2)
server-identifier: 192.168.2.1
lease-time: 86400 ( 1d )
renewal-time: 43200 ( 12h )
rebinding-time: 75600 ( 21h )
netmask: 255.255.255.0
broadcast: 192.168.2.255
domain-name: "local"
dns-server: 192.168.2.2
router: 192.168.2.1
--- end of options ---
* Received 300 bytes from eth0:192.168.1.1
Offered IP address: 192.168.1.241
Server IP address: 192.168.1.1
Relay-agent IP address: N/A
BOOTP server: (empty)
BOOTP file: (empty)
DHCP options:
Message type: DHCPOFFER (2)
server-identifier: 192.168.1.1
lease-time: 86400 ( 1d )
renewal-time: 43200 ( 12h )
rebinding-time: 75600 ( 21h )
netmask: 255.255.255.0
broadcast: 192.168.1.255
dns-server: 192.168.1.1
wpad-server: <cntrl sequence> (length 1)
router: 192.168.1.1
--- end of options ---
DHCP packets received on interface lo: 0
DHCP packets received on interface wlan0: 0
DHCP packets received on interface eth0: 2
Can we get a debug token from this other instance, please?
Edit: not saying that is the cause of the issue - but that sticks out as odd for me. Could be causing issues with the web interface.
Another place to check - developer console of your web browser. Look for any errors in the console or network tabs, specifically scripts not loading. From the screenshots it looks as though the CSS is unable to load...
It's possibly (but not definitely) indicative of a file system issue. If it were me, and it weren't too much hassle, I'd reflash the SD card and start again