Thank you for pointing that out. I noticed that before, and I wondered if this could be the problem. It just doesn't explain to me why 192.168.1.236/admin is unreachable. (Or does it?)
Now, I should mention that untill yesterday I had Pi-Hole running on a different Pi (Zero W), but it burned when I connected it to a faulty power supply. So now I am trying to run Pi-Hole on my HomeAutomation RPI 3B.
So, router config has not been changed in the meanwhile. The same DNS config (showing in image below) was used in the previous situation, which worked.
So could it be that this secondary DNS entry is hardprogrammed somewhere in my HomeAutomation RPI?
And is it possible that this also causes 192.168.1.236/admin not to be found?
Try and fill in Pi-hole's IP as Secondary DNS as well, or use 0.0.0.0 if your router insists on IPs being different.
No.
Though it does explain why you cannot access http://pi.hole/admin at times (since only Pi-hole is providing resolution for that name), Pi-hole's web UI should always be available via its IP address.
You'd have to look for other causes, like a double IP definition in your router or your browser's auto-completion or maybe just a typo...
You either have an IP address conflict in your network, or something is blocking access to your Pi-hole.
Check your router for address conflicts and your Pi-hole machine's firewall settings.