Pi-hole isn't blocking

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First step - manually map the DNS for that client to Pi-Hole, then verify that the DNS queries are going to Pi-Hole.

If that works, then work on your router settings to get the network DNS assigned to Pi-Hole. Typically in the DHCP tab of the router.

How do I configure my devices to use Pi-hole as their DNS server?

Three methods Generally, there are three different methods that will enable devices on your network to be protected by Pi-hole. 1. Define Pi-hole's IP address as the only DNS entry in the router Rationale Only is italicized here for a reason: Pi-hole needs to be the only DNS server because it intercepts queries and decides whether or not they should be blocked. If you have other DNS servers configured, you may be sent to the correct domain, bypassing Pi-hole completely. Because of this, we…