If you have IPv6 disabled, you aren't getting any IPv6 traffic in/out of your network.
Your debug log shows that Pi-hole is working and processing DNS traffic:
[2021-06-11 08:59:20.679 529M] Imported 21566 queries from the long-term database
[2021-06-11 08:59:20.682 529M] -> Total DNS queries: 21566
[2021-06-11 08:59:20.682 529M] -> Cached DNS queries: 4572
[2021-06-11 08:59:20.682 529M] -> Forwarded DNS queries: 12052
[2021-06-11 08:59:20.683 529M] -> Blocked DNS queries: 4699
[2021-06-11 08:59:20.683 529M] -> Unknown DNS queries: 0
[2021-06-11 08:59:20.683 529M] -> Unique domains: 1788
[2021-06-11 08:59:20.683 529M] -> Unique clients: 11
[2021-06-11 08:59:20.683 529M] -> Known forward destinations: 3
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