There are several methods to confirm redirection is working:
- from a machine, other than the pihole.
- start nslookup
- change the server to 8.8.8.8
- resolve a domain
The pihole query log will show DNS resolution has been performed by pihole
- Install wireshark (there is a portable version). As explained in this topic, the chromecast will think the reply is coming from 8.8.8.8, but the wireshark log will show the request is actually answered by pihole.