Enable pihole's DHCP server. It should set the DNS server to pihole's address. You can check by running ipconfig /all (on a Windows CMD prompt) and checking the DHCP and DNS info.
Especially if you set the DHCP range to cover your pihole static IP, you could set the pihole IP as a static address in pihole DHCP. Not sure if truly needed but seems to make sense.
Here's the overview: