I'm using windows 7 and already disabled Ipv6 on windows (if this helps) and set pi-hole ip as DNS and dhcp server.
I block listed ad domain that are showing up on speedtest.net and ads-blocker.com (www.googleadservices.com) (googleads.g.doubleclick.net) and it's still showing up, but pihole -t says its being blocked.
Look in /var/log/pihole.log for the queries from IP 192.168.0.5 for queries and replies for one of the two domains you are testing, and post the output here.
Dec 24 03:57:43 dnsmasq[9745]: query[A] www.googleadservices.com from 192.168.0.5
Dec 24 03:57:43 dnsmasq[9745]: exactly blacklisted www.googleadservices.com is 0.0.0.0
Dec 24 03:57:43 dnsmasq[9745]: query[AAAA] www.googleadservices.com from 192.168.0.5
Dec 24 03:57:43 dnsmasq[9745]: exactly blacklisted www.googleadservices.com is ::
Dec 24 03:58:10 dnsmasq[9745]: query[A] googleads.g.doubleclick.net from 192.168.0.5
Dec 24 03:58:10 dnsmasq[9745]: exactly blacklisted googleads.g.doubleclick.net is 0.0.0.0
Dec 24 03:58:10 dnsmasq[9745]: query[AAAA] googleads.g.doubleclick.net from 192.168.0.5
Dec 24 03:58:10 dnsmasq[9745]: exactly blacklisted googleads.g.doubleclick.net is ::
I originally have uBlock origin but I wanted to test if pi-hole does block ads on my browser but then ads starts showing up so i thought it was not working fine, I guess I'll just use uBlock origin for my desktop