Please tail the pihole log with this command from the command line, and then open that website on the iPhone and then post the output of the tail.
pihole -t
There is a bunch of red highlighted 0.0.0.0
Microsoft.var queries
If this is all you saw, then the iPhone is getting it's DNS elsewhere. Possibilities include an IPv6 DNS from the router, a VPN turned on, data on the cellular network and not on WiFI, a DNS service like 1.1.1.1 running, etc.
That was the solution I had 1.1.1.1 as a vpn profile running in background. Sorry I wasted your time for something as simple as that. Thank you very much
Glad it's resolved and your iPhone isn't seeing (many) ads.
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