I don't have anything Android to test on, but this article, while aimed at blacklisting, can be used in the exact same manner to determine domains to whitelist.
Block ads or fix broken sites
This FAQ is written in the context of finding out how to block an ad that isn't blocked automatically, but the same steps can be used to troubleshoot issues with sites that don't function properly. An example is that sometimes certain payment gateways try to collect metrics on the sale, but these domains are blocked by Pi-hole, so the payment cannot be processed. Also, some links send you through several referrers and if one of them is blocked, you may land on a …