by testing my DNS server(s) utilizing DNS Benchmark I figured that the Pi-Hole would block the wildcard-blocked apple.com, all lower case, but it would NOT block Apple.com, starting with upper case!
As far as I understand the definition of the domain name system it should totally be case insensitive:
Note that while upper and lower case letters are allowed in domain
names, no significance is attached to the case. That is, two names with
the same spelling but different case are to be treated as if identical.
Typing "Apple.com" in Chrome's Omnibox would result in Chrome (like all browsers) automatically querying the lower case "apple.com", receiving the IP of the Pi-Hole because the domain is blocked.
DNS Benchmark on the other hand queries "Apple.com" and a bunch of other popular domains ALL starting with a capital letter. In the query log it shows up as "OK" instead as "Pi-holed".
I tried to reproduce this and confirmed that the Pi-hole DNS server is indeed case insensitive. In your case, the query log page gives a wrong positive although the domain actually got blocked.