I wasted much time "assuming" the DNS addresses in the Netgear Orbi were actually prioritize. I'd put the Pi-hole as Primary, then rolled down my ISP's primary & secondary to the secondary & third slots. Trying to have these as autobackup when/if the Raspberry Pi was not available. Turns out the Orbi would then just use the addresses it knew, not sending most requests to Pi-hole. Before giving up and deciding Pi-hole didn't work, I tried removing the other DNS addresses from the router and found the real problem. Here's hoping this helps others? Have posted this with Netgear but not expecting speedy results?
I understand this. It's a matter of interpretation of Primary, Secondary, etc. I thought, incorrectly in the case of the Orbi, these multiple address would be prioritized. Primary would be used if available, etc., down the chain. And the others would be there as backup. I'm told Netgear uses dnsmasq which even has a prioritizing option which apparently isn't used. But in my opinion should be!