I get it to work after reboot. I dont know if its right way but:
I edit: /usr/local/etc/rc.d/S99pihole.sh restart
Add two lines for start and stop pihole-FTL like this:
#!/bin/sh
. /etc.defaults/rc.subr
case $1 in
start)
/var/packages/debian-chroot/scripts/start-stop-status start
chroot /volume1/@appstore/debian-chroot/var/chroottarget service cron start
chroot /volume1/@appstore/debian-chroot/var/chroottarget service dnsmasq start
chroot /volume1/@appstore/debian-chroot/var/chroottarget service lighttpd start
**chroot /volume1/@appstore/debian-chroot/var/chroottarget service pihole-FTL start**
;;
stop)
chroot /volume1/@appstore/debian-chroot/var/chroottarget service cron stop
chroot /volume1/@appstore/debian-chroot/var/chroottarget service dnsmasq stop
chroot /volume1/@appstore/debian-chroot/var/chroottarget service lighttpd stop
**chroot /volume1/@appstore/debian-chroot/var/chroottarget service pihole-FTL stop**
/var/packages/debian-chroot/scripts/start-stop-status stop
;;
restart)
$0 stop
sleep 1
$0 start
;;
*)
echo "Usage: $0 start|stop|restart"
;;
esac