Host website alongside Pi-Hole interface

Yes. As indicated in the top of that file:

###############################################################################
#     FILE AUTOMATICALLY OVERWRITTEN BY PI-HOLE INSTALL/UPDATE PROCEDURE.     #
# ANY CHANGES MADE TO THIS FILE AFTER INSTALL WILL BE LOST ON THE NEXT UPDATE #
#                                                                             #
#              CHANGES SHOULD BE MADE IN A SEPARATE CONFIG FILE:              #
#                         /etc/lighttpd/external.conf                         #
###############################################################################