Excessive requests for dns.msftncsi.com

ASUS does use a phone home capability on their routers (aiCloud is one technology.) There are a few domains that most modern ASUS routers use to check for firmware updates, and to provide "added services" for purchasers. as DL6ER mentioned, you may be able to find the culprit via the web interface on the Pi-hole, depending on how you have the router configured for DNS.